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Issue 3, 2019
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The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

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Abstract

Li and H2O encapsulated in the uranyl peroxide cage cluster U24 at 110 K are in square pyramidal and octahedral coordination environments, as dictated by the symmetry and topology of U24, in contrast to Li cations between the cages that are tetrahedrally coordinated by H2O. The ordered distribution of Li found here deviates from earlier studies at higher temperatures that reported a dynamic distribution.

Graphical abstract: The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

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Publication details

The article was received on 16 Oct 2018, accepted on 30 Nov 2018 and first published on 03 Dec 2018


Article type: Communication
DOI: 10.1039/C8CE01774C
Citation: CrystEngComm, 2019,21, 390-393

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    The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

    H. Traustason, S. M. Aksenov and P. C. Burns, CrystEngComm, 2019, 21, 390
    DOI: 10.1039/C8CE01774C

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