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Issue 3, 2020
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A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

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Abstract

A simple Co(II)-based amine–borane dehydropolymerisation catalyst system is reported that operates at low loadings, to selectively give (H2BNMeH)n polymer on scale, with catalyst control over Mn, narrow dispersities and low residual metal content.

Graphical abstract: A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

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Article information


Submitted
13 Nov 2019
Accepted
02 Dec 2019
First published
03 Dec 2019

Chem. Commun., 2020,56, 482-485
Article type
Communication

A simple cobalt-based catalyst system for the controlled dehydropolymerisation of H3B·NMeH2 on the gram-scale

T. M. Boyd, K. A. Andrea, K. Baston, A. Johnson, D. E. Ryan and A. S. Weller, Chem. Commun., 2020, 56, 482
DOI: 10.1039/C9CC08864D

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