Jump to main content
Jump to site search

Issue 97, 2019
Previous Article Next Article

Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

Author affiliations

Abstract

The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}25, Me-IPr = C{(NDipp)CMe}26; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids. Calculations suggest that 5 and 6 are electrophilic, which has been demonstrated by the reaction of 5 with an NHC nucleophile (IMe4), affording the Lewis adduct [{(IPr)C(Ph)}As(IMe4)]Fe(CO)4 (7) (IMe4 = C(NMeCMe)2).

Graphical abstract: Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 Nov 2019, accepted on 08 Nov 2019 and first published on 11 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08630G
Chem. Commun., 2019,55, 14669-14672

  •   Request permissions

    Electrophilic terminal arsinidene-iron(0) complexes with a two-coordinated arsenic atom

    M. K. Sharma, B. Neumann, H. Stammler, D. M. Andrada and R. S. Ghadwal, Chem. Commun., 2019, 55, 14669
    DOI: 10.1039/C9CC08630G

Search articles by author

Spotlight

Advertisements