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Issue 98, 2019
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One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

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Abstract

Herein, we report a new method for the one-pot syntheses of sulfonyl fluorides. Addition of an alkyl, aryl, or heteroaryl Grignard to a solution of sulfuryl fluoride at ambient temperature affords the desired sulfonyl fluorides in 18–78% yield. Furthermore, this method is applicable for in situ sequential reactions, whereby the Grignard reagent can be converted to the corresponding diarylsulfone, sulfonate ester, or sulfonamide in a one-pot process.

Graphical abstract: One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

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Article information


Submitted
30 Oct 2019
Accepted
15 Nov 2019
First published
15 Nov 2019

Chem. Commun., 2019,55, 14753-14756
Article type
Communication

One-pot fluorosulfurylation of Grignard reagents using sulfuryl fluoride

C. Lee, N. D. Ball and G. M. Sammis, Chem. Commun., 2019, 55, 14753
DOI: 10.1039/C9CC08487H

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