Novel bis(isoselenocarbonyl) complexes [W2Pt(μ-CSe)2(CO)4(L2)(Tp*)2] (L2 = cyclooctadiene, norbornadiene) eliminate the diene upon heating to provide [W2Pt(μ-CSe)2(CO)4(Tp*)2], in which the CSe ligands close to bridge W–Pt bonds in a σ–π mode that may be re-opened by addition of new ligands (CNR: R = tBu, C6H2Me3) to re-establish the isoselenocarbonyl coordination in [W2Pt(μ-CSe)2(CO)4(CNR)2(Tp*)2].
B. J. Frogley, A. F. Hill and L. J. Watson, Chem. Commun., 2019, 55, 14450 DOI: 10.1039/C9CC07757J
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