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Four consecutive reactions in one pot: cascade formation of an unprecedented triphosphatricyclo[3.2.1.02,7]oct-3-ene

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Abstract

A hitherto unknown triphosphatricyclo[3.2.1.02,7]oct-3-ene was obtained in high yield by a total of four consecutive pericyclic reactions from di-2-pyrone and excess TMS-C[triple bond, length as m-dash]P. DFT calculations gave insight into the reaction mechanism. The chiral phosphorus cage readily forms coordination compounds with Au(I) and Cu(I).

Graphical abstract: Four consecutive reactions in one pot: cascade formation of an unprecedented triphosphatricyclo[3.2.1.02,7]oct-3-ene

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Publication details

The article was received on 23 Sep 2019, accepted on 08 Oct 2019 and first published on 09 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07462G
Chem. Commun., 2019, Advance Article

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    Four consecutive reactions in one pot: cascade formation of an unprecedented triphosphatricyclo[3.2.1.02,7]oct-3-ene

    S. Giese, D. Buzsáki, L. Nyulászi and C. Müller, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07462G

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