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Issue 97, 2019
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Highly stereoselective synthesis of aryl/heteroaryl-C-nucleosides via the merger of photoredox and nickel catalysis

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Abstract

A photoredox/nickel dual-catalyzed decarboxylative cross-coupling reaction of anomeric ribosyl/deoxyribosyl acids with aryl/heteroaryl bromides has been developed. The reaction proceeds smoothly under visible-light irradiation and features the using of cost-effective and easily handled catalysts and starting materials, which allows the highly stereoselective synthesis of diverse aryl/heteroaryl-C-nucleosides in moderate to high yields.

Graphical abstract: Highly stereoselective synthesis of aryl/heteroaryl-C-nucleosides via the merger of photoredox and nickel catalysis

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Publication details

The article was received on 13 Sep 2019, accepted on 13 Nov 2019 and first published on 14 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07184A
Chem. Commun., 2019,55, 14657-14660

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    Highly stereoselective synthesis of aryl/heteroaryl-C-nucleosides via the merger of photoredox and nickel catalysis

    Y. Ma, S. Liu, Y. Xi, H. Li, K. Yang, Z. Cheng, W. Wang and Y. Zhang, Chem. Commun., 2019, 55, 14657
    DOI: 10.1039/C9CC07184A

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