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Issue 91, 2019
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Process-tracing study on the post-assembly modification of poly-NHC-based metallosupramolecular cylinders with tunable aggregation-induced emission

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Abstract

In this work, we demonstrate the design and fabrication of a series of cylinder-like, hexazido-terminated MI–CNHC (M = Ag, Au) complexes. Moreover, we present for the first time a process-tracing and aggregation-induced emission (AIE) study of a covalent postassembly modification (PAM) process of the AuI–CNHC cylinders, highlighting the excellent versatility and complexity of functionalised poly-NHC compounds as a new type of molecular platform for novel applications.

Graphical abstract: Process-tracing study on the post-assembly modification of poly-NHC-based metallosupramolecular cylinders with tunable aggregation-induced emission

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Publication details

The article was received on 11 Sep 2019, accepted on 21 Oct 2019 and first published on 21 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07113J
Chem. Commun., 2019,55, 13689-13692

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    Process-tracing study on the post-assembly modification of poly-NHC-based metallosupramolecular cylinders with tunable aggregation-induced emission

    Y. Wang, S. Bai, Y. Wang and Y. Han, Chem. Commun., 2019, 55, 13689
    DOI: 10.1039/C9CC07113J

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