Issue 80, 2019
From the journal:

Chemical Communications

The Mn-catalyzed paired electrochemical facile oxychlorination of styrenes via the oxygen reduction reaction†

Siyu Tian,a   Xiaofei Jia, ORCID logo b   Ling Wang,a   Baoying Li,a   Siyuan Liu, ORCID logo a   Li Ma,a   Wei Gao,a   Yingqin Wei ORCID logo a  and  Jianbin Chen ORCID logo *a  

* Corresponding authors

a Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, P. R. China
E-mail: jchen@qlu.edu.cn

b Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Abstract

Reported herein is the electrochemical engendering of chlorine radicals by a manganese catalyst with a controllable pattern, and inexpensive MgCl2 as the chlorine source. In combination with the oxygen reduction reaction, chloroacetophenones were synthesized with abundant styrene as the feedstock in good to excellent yields.

Graphical abstract: The Mn-catalyzed paired electrochemical facile oxychlorination of styrenes via the oxygen reduction reaction

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Article information

DOI
https://doi.org/10.1039/C9CC06746A
Article type
Communication
Submitted
30 Aug 2019
Accepted
10 Sep 2019
First published
11 Sep 2019

Chem. Commun., 2019,55, 12104-12107

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The Mn-catalyzed paired electrochemical facile oxychlorination of styrenes via the oxygen reduction reaction

S. Tian, X. Jia, L. Wang, B. Li, S. Liu, L. Ma, W. Gao, Y. Wei and J. Chen, Chem. Commun., 2019, 55, 12104 DOI: 10.1039/C9CC06746A

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