Superstructured metallocorroles for electrochemical CO2 reduction

Woormileela Sinha; Atif Mahammed; Natalia Fridman; Yael Diskin-Posner; Linda J. W. Shimon; Zeev Gross

doi:10.1039/C9CC06645D

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Superstructured metallocorroles for electrochemical CO₂ reduction†

Woormileela Sinha,

^a Atif Mahammed,^a Natalia Fridman,^a Yael Diskin-Posner,

^b Linda J. W. Shimon

^b and Zeev Gross

*^a

Author affiliations

* Corresponding authors

^a Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Haifa, Israel
E-mail: chr10zg@technion.ac.il

^b Department of Chemical Research Support, Weizmann Institute of Science, Rehovot, Israel

Abstract

Cobalt and iron complexes of corroles with tyrosine-like proton-transfer-relay moieties in proximity to the metal center have been prepared and fully characterized. The (nitrosyl)iron complex performs very well as an electrocatalyst for the reduction of CO₂ to CO.

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Article information

DOI: https://doi.org/10.1039/C9CC06645D
Article type: Communication
Submitted: 26 Aug 2019
Accepted: 06 Sep 2019
First published: 06 Sep 2019

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Chem. Commun., 2019,55, 11912-11915

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Superstructured metallocorroles for electrochemical CO₂ reduction

W. Sinha, A. Mahammed, N. Fridman, Y. Diskin-Posner, L. J. W. Shimon and Z. Gross, Chem. Commun., 2019, 55, 11912 DOI: 10.1039/C9CC06645D

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Chemical Communications