Issue 98, 2019
From the journal:

Chemical Communications

Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations†

Natalie Dehnhardt, ORCID logo a   Jan-Niclas Luy,a   Marvin Szabo,a   Mirco Wende,a   Ralf Tonner ORCID logo *a  and  Johanna Heine ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Material Sciences Center, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany
E-mail: tonner@chemie.uni-marburg.de, johanna.heine@chemie.uni-marburg.de

Abstract

(Me2C[double bond, length as m-dash]NMe2)Bi2I7 represents a new layered organic–inorganic iodido bismuthate. It displays an unprecedented anion topology, a low band gap and good stability. Advanced electronic structure analysis finds the I⋯I interactions to be decisive for the compound's structural and electronic properties.

Graphical abstract: Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

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Article information

DOI
https://doi.org/10.1039/C9CC06625J
Article type
Communication
Submitted
26 Aug 2019
Accepted
26 Oct 2019
First published
04 Nov 2019

Chem. Commun., 2019,55, 14725-14728

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Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

N. Dehnhardt, J. Luy, M. Szabo, M. Wende, R. Tonner and J. Heine, Chem. Commun., 2019, 55, 14725 DOI: 10.1039/C9CC06625J

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