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Revisiting the water sorption isotherm of MOF using electrical measurements

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Abstract

Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling further established the relationship between the evolutive water–hydrogen bonded network and the “electrical” isotherm for this water-mediated proton conducting MOF.

Graphical abstract: Revisiting the water sorption isotherm of MOF using electrical measurements

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Publication details

The article was received on 02 Aug 2019, accepted on 09 Oct 2019 and first published on 09 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06012J
Chem. Commun., 2019, Advance Article

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    Revisiting the water sorption isotherm of MOF using electrical measurements

    S. Nandi, H. Aggarwal, M. Wahiduzzaman, Y. Belmabkhout, G. Maurin, M. Eddaoudi and S. Devautour-Vinot, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06012J

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