Issue 76, 2019
From the journal:

Chemical Communications

Regioselective intramolecular Markovnikov and anti-Markovnikov hydrofunctionalization of alkenes via photoredox catalysis†

Hongyu Wang,‡a   Yunquan Man,‡a   Yanan Xiang,a   Kaiye Wang,a   Na Li ORCID logo *a  and  Bo Tang ORCID logo *a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Institute of Molecular and Nano Science, Shandong Normal University, Jinan, P. R. China
E-mail: lina@sdnu.edu.cn, tangb@sdnu.edu.cn

Abstract

Highly regioselective Markovnikov hydrofunctionalization of alkenes was successfully realized via photoredox catalysis by introducing a urea group and fine tuning the hydrogen atom transfer catalysts. The anti-Markovnikov hydroamination of alkenes was also achieved with high yields and stereoselectivities in this work.

Graphical abstract: Regioselective intramolecular Markovnikov and anti-Markovnikov hydrofunctionalization of alkenes via photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/C9CC05902D
Article type
Communication
Submitted
29 Jul 2019
Accepted
26 Aug 2019
First published
26 Aug 2019

Chem. Commun., 2019,55, 11426-11429

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Regioselective intramolecular Markovnikov and anti-Markovnikov hydrofunctionalization of alkenes via photoredox catalysis

H. Wang, Y. Man, Y. Xiang, K. Wang, N. Li and B. Tang, Chem. Commun., 2019, 55, 11426 DOI: 10.1039/C9CC05902D

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