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Dioxygen-Triggered Oxidative Cleavage of C-S Bond towards C-N Bond Formation

Abstract

The research on the cleavage of C-C bond has been well developed. By comparision with this, the activation of C-S bond remains challenging. Herein, dioxygen-triggered oxidative cleavage of C-S bond has been achieved, delivering a series of N-containing heterocyclic compounds which are frequently found in pesticides and pharmaceuticals. Additionally, the potential ultility of this protocol was further demonstrated by gram-scale experiment. Mechanistically, dioxygen plays a key role in the cleavage of C-S bond towards C-N bond formation.

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Publication details

The article was received on 23 Jul 2019, accepted on 11 Sep 2019 and first published on 12 Sep 2019


Article type: Communication
DOI: 10.1039/C9CC05707B
Chem. Commun., 2019, Accepted Manuscript

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    Dioxygen-Triggered Oxidative Cleavage of C-S Bond towards C-N Bond Formation

    Z. Lv, H. Wang, Z. Quan, Y. Gao and A. Lei, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC05707B

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