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Issue 82, 2019
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Dioxygen-triggered oxidative cleavage of the C–S bond towards C–N bond formation

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Abstract

Research on the cleavage of C–C bonds has been well developed. By comparison with this, the activation of C–S bonds remains challenging. Herein, dioxygen-triggered oxidative cleavage of C–S bonds has been achieved, delivering a series of N-containing heterocyclic compounds that are frequently found in pesticides and pharmaceuticals. Additionally, the potential utility of this protocol was further demonstrated by a gram-scale experiment. Mechanistically, dioxygen plays a key role in the cleavage of C–S bonds towards C–N bond formation.

Graphical abstract: Dioxygen-triggered oxidative cleavage of the C–S bond towards C–N bond formation

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Publication details

The article was received on 23 Jul 2019, accepted on 11 Sep 2019 and first published on 12 Sep 2019


Article type: Communication
DOI: 10.1039/C9CC05707B
Chem. Commun., 2019,55, 12332-12335

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    Dioxygen-triggered oxidative cleavage of the C–S bond towards C–N bond formation

    Z. Lv, H. Wang, Z. Quan, Y. Gao and A. Lei, Chem. Commun., 2019, 55, 12332
    DOI: 10.1039/C9CC05707B

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