Issue 71, 2019

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon–fluorine bond cleavage and carbon–silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Graphical abstract: Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2019
Accepted
05 Aug 2019
First published
05 Aug 2019

Chem. Commun., 2019,55, 10507-10510

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

X. Wang, Z. Wang and Y. Nishihara, Chem. Commun., 2019, 55, 10507 DOI: 10.1039/C9CC05325E

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