Issue 77, 2019
From the journal:

Chemical Communications

Construction of a short metallofullerene-peapod with a spin probe†

Chong Zhao, ORCID logo ab   Haibing Meng, ORCID logo ab   Mingzhe Nie, ORCID logo ab   Qiang Huang,c   Pingwu Du, ORCID logo *c   Chunru Wang ORCID logo *a  and  Taishan Wang ORCID logo *a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, Beijing, China
E-mail: crwang@iccas.ac.cn, wangtais@iccas.ac.cn

b University of Chinese Academy of Sciences, Beijing, China

c Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China, Hefei, China
E-mail: dupingwu@ustc.edu.cn

Abstract

A short metallofullere-peapod of Y2@C79N⊂[4]CHBC was constructed. The strong confinement effect from the large π-extended [4]CHBC nanoring induces molecular orientation of the wrapped Y2@C79N, which can be sensed by a Y2@C79N spin probe. The low susceptibility of the spin phase memory time (Tm) for the Y2@C79N spin was also found in a confined space.

Graphical abstract: Construction of a short metallofullerene-peapod with a spin probe

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Article information

DOI
https://doi.org/10.1039/C9CC05220H
Article type
Communication
Submitted
08 Jul 2019
Accepted
27 Aug 2019
First published
28 Aug 2019

Chem. Commun., 2019,55, 11511-11514

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Construction of a short metallofullerene-peapod with a spin probe

C. Zhao, H. Meng, M. Nie, Q. Huang, P. Du, C. Wang and T. Wang, Chem. Commun., 2019, 55, 11511 DOI: 10.1039/C9CC05220H

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