Issue 58, 2019
From the journal:

Chemical Communications

Phase-competition-driven formation of hierarchical FeNiZn-MIL-88B-on-MOF-5 octapods displaying high selectivity for the RWGS reaction†

Qinwei Zhang,a   Zuobo Yang,a   Biaohua Chen*b  and  Xin Liang ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing, China
E-mail: liangxin@mail.buct.edu.cn

b College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
E-mail: chenbh@bjut.edu.cn

Abstract

Hierarchical MIL-88B-on-MOF-5 octapods were synthesized via a mechanism involving phase-competition-driven growth (PCDG). Dramatically different morphologies (nanocubes, octapods, flowers) were also produced by controlling the phase competition between MIL-88B and MOF-5. The octapod MOFs showed a high catalytic performance for the reverse water–gas shift (RWGS) reaction.

Graphical abstract: Phase-competition-driven formation of hierarchical FeNiZn-MIL-88B-on-MOF-5 octapods displaying high selectivity for the RWGS reaction

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Article information

DOI
https://doi.org/10.1039/C9CC03716K
Article type
Communication
Submitted
14 May 2019
Accepted
21 Jun 2019
First published
21 Jun 2019

Chem. Commun., 2019,55, 8450-8453

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Phase-competition-driven formation of hierarchical FeNiZn-MIL-88B-on-MOF-5 octapods displaying high selectivity for the RWGS reaction

Q. Zhang, Z. Yang, B. Chen and X. Liang, Chem. Commun., 2019, 55, 8450 DOI: 10.1039/C9CC03716K

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