A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H

Jixiang Ni; Yong Jiang; Zhenyu An; Jingfeng Lan; Rulong Yan

doi:10.1039/C9CC03096D

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A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)₂P(O)H†

Jixiang Ni,^a Yong Jiang,

^b Zhenyu An,^a Jingfeng Lan^a and Rulong Yan

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, People's Republic of China
E-mail: yanrl@lzu.edu.cn
Fax: +86-0931-8912596

^b School of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing, China

Abstract

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO)₂P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields.

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Article information

DOI: https://doi.org/10.1039/C9CC03096D
Article type: Communication
Submitted: 22 Apr 2019
Accepted: 28 May 2019
First published: 30 May 2019

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Chem. Commun., 2019,55, 7343-7345

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A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)₂P(O)H

J. Ni, Y. Jiang, Z. An, J. Lan and R. Yan, Chem. Commun., 2019, 55, 7343 DOI: 10.1039/C9CC03096D

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Chemical Communications