Issue 47, 2019
From the journal:

Chemical Communications

[Bi7M3(CO)3]2− (M = Co, Rh): a new architype of 10-vertex deltahedral hybrids by the unprecedented polycyclic η5-coordination addition of Bi73− and trimetallic fragments†

Zhenyu Li,ab   Dan Ouyangc  and  Li Xu ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences, Fujian 350002, Fuzhou, P. R. China
E-mail: xli@fjirsm.ac.cn

b University of the Chinese Academy of Science, Beijing, P. R. China

c Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fujian, Fuzhou, China

Abstract

Redox reactions of K5Bi4 and CpCo(CO)2/Rh(CO)2(acac) (acac = acetylacetonate) in ethylenediamine (en) yielded the first Bi73− adducts [Bi7M3(CO)3]2− (M = Co, 1a; Rh, 2a) that have a new architype 10-vertex deltahedral structure, resulting from the unprecedented polycyclic η5-coordination addition reaction of the Bi73− cage and three MCO+ fragments.

Graphical abstract: [Bi7M3(CO)3]2− (M = Co, Rh): a new architype of 10-vertex deltahedral hybrids by the unprecedented polycyclic η5-coordination addition of Bi73− and trimetallic fragments

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Article information

DOI
https://doi.org/10.1039/C9CC03079D
Article type
Communication
Submitted
20 Apr 2019
Accepted
10 May 2019
First published
14 May 2019

Chem. Commun., 2019,55, 6783-6786

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[Bi7M3(CO)3]2− (M = Co, Rh): a new architype of 10-vertex deltahedral hybrids by the unprecedented polycyclic η5-coordination addition of Bi73− and trimetallic fragments

Z. Li, D. Ouyang and L. Xu, Chem. Commun., 2019, 55, 6783 DOI: 10.1039/C9CC03079D

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