Jump to main content
Jump to site search

Issue 58, 2019
Previous Article Next Article

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Author affiliations

Abstract

Regioselective C–H oxidation of aliphatic molecules with synthetic catalysts is challenging. We incorporated substrate-recognition sites into a ruthenium porphyrin–heteroaromatic N-oxide catalytic system in order to characterise its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency.

Graphical abstract: Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Apr 2019, accepted on 10 Jun 2019 and first published on 14 Jun 2019


Article type: Communication
DOI: 10.1039/C9CC03041G
Chem. Commun., 2019,55, 8378-8381

  •   Request permissions

    Methylene chain ruler for evaluating the regioselectivity of a substrate-recognising oxidation catalyst

    S. Teramae, A. Kito, T. Shingaki, Y. Hamaguchi, Y. Yano, T. Nakayama, Y. Kobayashi, N. Kato, N. Umezawa, Y. Hisamatsu, T. Nagano and T. Higuchi, Chem. Commun., 2019, 55, 8378
    DOI: 10.1039/C9CC03041G

Search articles by author

Spotlight

Advertisements