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Abstract | Cited by

The different hydrogen bond interactions in two organic–inorganic hybrid manganese halide compounds, namely [A]2[MnBr4] (A = N-butyl-N-methylpyrrolidinium ([P14]+) for (1) and N-butyl-N-methylpiperidinium ([PP14]+) for (2)), lead to distinct photoluminescence quantum yields (81% for 1; 55% for 2). Further applications of luminescent 1 are also developed.

Graphical abstract: Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr4]2− anions and organic cations

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