From lithium to sodium: design of heterometallic molecular precursors for the NaMO2 cathode materials

Haixiang Han; Zheng Zhou; Jesse C. Carozza; Jeff Lengyel; Yuan Yao; Zheng Wei; Evgeny V. Dikarev

doi:10.1039/C9CC02836F

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From lithium to sodium: design of heterometallic molecular precursors for the NaMO₂ cathode materials†

Haixiang Han,

^ab Zheng Zhou,^a Jesse C. Carozza,^a Jeff Lengyel,^c Yuan Yao,^b Zheng Wei^a and Evgeny V. Dikarev

*^a

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* Corresponding authors

^a Department of Chemistry, University at Albany, State University of New York, 1400 Washington Ave., Albany, NY 12222, USA
E-mail: edikarev@albany.edu

^b Department of Materials Science and Engineering, Cornell University, NY 14850, USA

^c Department of Chemistry and Biochemistry, Florida State University, FL 32306, USA

Abstract

Based on the well-established model structure of Li₂M₂(tbaoac)₆, the first series of heterometallic molecular precursors Na₂M₂(tbaoac)₆(THF)₂ (M = Fe, Co, and Ni) have been designed and successfully utilized for the preparation of NaMO₂ oxide cathode materials of sodium-ion batteries.

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Article information

DOI: https://doi.org/10.1039/C9CC02836F
Article type: Communication
Submitted: 12 Apr 2019
Accepted: 30 May 2019
First published: 30 May 2019

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Chem. Commun., 2019,55, 7243-7246

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From lithium to sodium: design of heterometallic molecular precursors for the NaMO₂ cathode materials

H. Han, Z. Zhou, J. C. Carozza, J. Lengyel, Y. Yao, Z. Wei and E. V. Dikarev, Chem. Commun., 2019, 55, 7243 DOI: 10.1039/C9CC02836F

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