Issue 45, 2019
From the journal:

Chemical Communications

The application of spatially restricted geometries as a unique route to produce well-defined poly(vinyl pyrrolidones) via free radical polymerisation†

Magdalena Tarnacka, ORCID logo *ab   Paulina Maksym, ORCID logo ac   Andrzej Zięba,d   Anna Mielańczyk, ORCID logo e   Monika Geppert-Rybczyńska,f   Laia Leon-Boigues,b   Carmen Mijangos,*b   Kamil Kamiński*ac  and  Marian Paluchac  

* Corresponding authors

a Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice, Poland
E-mail: magdalena.tarnacka@smcebi.edu.pl, kamil.kaminski@us.edu.pl

b Instituto de Ciencia y Tecnología de Polímeros, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain
E-mail: cmijangos@ictp.csic.es

c Silesian Center of Education and Interdisciplinary Research, University of Silesia, ul. 75 Pulku Piechoty 1A, 41-500 Chorzow, Poland

d Department of Organic Chemistry, School of Pharmacy with the Division of Laboratory Medicine in Sosnowiec, Medical University of Silesia in Katowice, ul. Jagiellońska 4, 41-200 Sosnowiec, Poland

e Department of Physical Chemistry and Technology of Polymers, Faculty of Chemistry, Silesian University of Technology, ul. M. Strzody 9, 44-100 Gliwice, Poland

f Institute of Chemistry, University of Silesia, ul. Szkolna 9, 40-007 Katowice, Poland

Abstract

We report, for the first time, the metal-free green synthesis of linear poly(vinyl pyrrolidone) (PVP) homopolymers of molecular weight higher than 100 kg mol−1 and narrow dispersities via thermal and photo-induced free radical polymerisation carried out within alumina nanoporous membranes acting as “nanoreactors”.

Graphical abstract: The application of spatially restricted geometries as a unique route to produce well-defined poly(vinyl pyrrolidones) via free radical polymerisation

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Article information

DOI
https://doi.org/10.1039/C9CC02625H
Article type
Communication
Submitted
04 Apr 2019
Accepted
01 May 2019
First published
01 May 2019

Chem. Commun., 2019,55, 6441-6444

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The application of spatially restricted geometries as a unique route to produce well-defined poly(vinyl pyrrolidones) via free radical polymerisation

M. Tarnacka, P. Maksym, A. Zięba, A. Mielańczyk, M. Geppert-Rybczyńska, L. Leon-Boigues, C. Mijangos, K. Kamiński and M. Paluch, Chem. Commun., 2019, 55, 6441 DOI: 10.1039/C9CC02625H

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