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Issue 44, 2019
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Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

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Abstract

Cycloaddition reactions of carbynes in metallacycles with π-bond substrates have been rarely reported. We report the first [2+2] cycloaddition of metallapentalynes with nitrosoarenes to obtain the first metallapentalenoxazetes, and their photophysical and electrochemical properties were studied by UV-Vis spectroscopy and cyclic voltammetry with the help of theoretical calculations.

Graphical abstract: Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

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Publication details

The article was received on 03 Apr 2019, accepted on 03 May 2019 and first published on 04 May 2019


Article type: Communication
DOI: 10.1039/C9CC02594D
Chem. Commun., 2019,55, 6237-6240

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    Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

    Z. Deng, C. Zhu, Y. Hua, G. He, Y. Guo, R. Lu, X. Cao, J. Chen and H. Xia, Chem. Commun., 2019, 55, 6237
    DOI: 10.1039/C9CC02594D

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