Issue 46, 2019

A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

Abstract

We report a robust and rigid etb-type metal–organic framework, in which its pore surface is decorated with flexible ethoxyl groups. It shows unprecedentedly selective adsorption of acetone (ETN value of 0.355, kinetic diameter of 4.6 Å) over methanol (ETN value of 0.762, kinetic diameter of 3.6 Å) for their azeotropic mixture.

Graphical abstract: A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

Supplementary files

Article information

Article type
Communication
Submitted
29 Mar 2019
Accepted
25 Apr 2019
First published
03 May 2019

Chem. Commun., 2019,55, 6495-6498

A robust etb-type metal–organic framework showing polarity-exclusive adsorption of acetone over methanol for their azeotropic mixture

H. Hu, J. Zhu, F. Yang, Z. Chen, M. Deng, L. Weng, Y. Ling and Y. Zhou, Chem. Commun., 2019, 55, 6495 DOI: 10.1039/C9CC02439E

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