Issue 40, 2019
From the journal:

Chemical Communications

A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines†

Xu-Sheng Du,a   Qiong Jia,a   Chun-Yu Wang, ORCID logo b   Kamel Meguellati ORCID logo *a  and  Ying-Wei Yang ORCID logo *a  

* Corresponding authors

a International Joint Research Laboratory of Nano-Micro Architecture Chemistry (NMAC), College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China
E-mail: kamel_m@jlu.edu.cn, ywyang@jlu.edu.cn

b State Key Laboratory of Supramolecular Structure and Materials, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China

Abstract

We report a new mono-armed pillar[5]arene with the amino-substituent self-included in the pillarene cavity, which can stabilize the hemiaminals and imines formed from the reaction of aliphatic amines and aldehydes as monitored by mass spectroscopy.

Graphical abstract: A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

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Article information

DOI
https://doi.org/10.1039/C9CC01947B
Article type
Communication
Submitted
10 Mar 2019
Accepted
17 Apr 2019
First published
18 Apr 2019

Chem. Commun., 2019,55, 5736-5739

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A pillar[5]arene with an amino-terminated arm stabilizes the formation of aliphatic hemiaminals and imines

X. Du, Q. Jia, C. Wang, K. Meguellati and Y. Yang, Chem. Commun., 2019, 55, 5736 DOI: 10.1039/C9CC01947B

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