Polymers of intrinsic microporosity (PIM-1) have an appropriate pore size to reduce the solvation number of Li ions in electrolytes. This unique pore structure of PIM-1 as a solid interphase can suppress transport of solvent and consequently unwanted chemical reactions at the interface of anodes, thereby extending the cycle life of Li metal anodes.
G. H. Moon, H. J. Kim, I. S. Chae, S. C. Park, B. S. Kim, J. Jang, H. Kim and Y. S. Kang, Chem. Commun., 2019, 55, 6313 DOI: 10.1039/C9CC01329F
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