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Issue 24, 2019
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Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

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Abstract

We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.

Graphical abstract: Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

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Publication details

The article was received on 21 Jan 2019, accepted on 12 Feb 2019 and first published on 04 Mar 2019


Article type: Communication
DOI: 10.1039/C9CC00492K
Chem. Commun., 2019,55, 3489-3492
  • Open access: Creative Commons BY-NC license
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    Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

    V. R. Yatham, P. Bellotti and B. König, Chem. Commun., 2019, 55, 3489
    DOI: 10.1039/C9CC00492K

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