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Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers

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Abstract

Dibenzo[b,e]phosphindolizines 1 were successfully synthesized by a ring-closing metathesis of benzo[b]phosphole chalcogenides 2a–2c with two vinyl tethers (for chalcogen analogs 1a–1c), and by a deselenization reaction (for lone-pair analog 1d). The structures, properties, and bowl inversion derived from a phosphorus atom were fully investigated.

Graphical abstract: Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers

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Publication details

The article was received on 18 Jan 2019, accepted on 11 Mar 2019 and first published on 13 Mar 2019


Article type: Communication
DOI: 10.1039/C9CC00463G
Citation: Chem. Commun., 2019, Advance Article

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    Dibenzo[b,e]phosphindolizines synthesized by a ring-closing metathesis of benzo[b]phospholes with two vinyl tethers

    A. Tsurusaki, H. Matsumoto and K. Kamikawa, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC00463G

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