Issue 18, 2019
From the journal:

Chemical Communications

Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex†

Zhe Huang,a   Gengwen Tan,b   Chao Chen,b   Wen-Xiong Zhang, ORCID logo a   Xinping Wang ORCID logo b  and  Zhenfeng Xi ORCID logo *a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: zfxi@pku.edu.cn

b State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Abstract

Selective reduction of 1,5-diazacyclooctatetraenes with potassium or a Co(I) complex was achieved to provide the first structurally well-defined aromatic 1,5-diazacyclooctatetraenyl dianion or a novel dinuclear Co(II) complex bridged by a bipyrrolinyl dianion, respectively.

Graphical abstract: Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(ii) complex

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Article information

DOI
https://doi.org/10.1039/C9CC00075E
Article type
Communication
Submitted
04 Jan 2019
Accepted
04 Feb 2019
First published
04 Feb 2019

Chem. Commun., 2019,55, 2648-2651

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Selective reduction of 1,5-diazacyclooctatetraenes: synthesis and structures of aromatic diazacyclooctatetraenyl dianions and a 2,6-bipyrrolinyl dianionic Co(II) complex

Z. Huang, G. Tan, C. Chen, W. Zhang, X. Wang and Z. Xi, Chem. Commun., 2019, 55, 2648 DOI: 10.1039/C9CC00075E

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