Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

Hui Zhang; Maolin Huang; Jie Wen; Yanping Li; Airong Li; Lianhong Zhang; Arshid Mahmood Ali; Yadong Li

doi:10.1039/C9CC00003H

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Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation†

Hui Zhang,

*^a Maolin Huang,^a Jie Wen,^a Yanping Li,

^a Airong Li,^a Lianhong Zhang,^a Arshid Mahmood Ali^b and Yadong Li^c

Author affiliations

* Corresponding authors

^a The Center of New Energy Materials and Technology, College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
E-mail: huizhang@swpu.edu.cn

^b Department of Chemical & Materials Engineering, King Abdulaziz University, Jeddah 72523, Kingdom of Saudi Arabia

^c Department of Chemistry, Tsinghua University, Beijing 100084, China

Abstract

Ultrafine sub-3 nm Rh nanoclusters confined within a metal–organic framework (UIO-66) were constructed through a double-solvent host–guest strategy and achieved superior hydrogen generation via ammonia borane hydrolysis compared with Rh nanoclusters dispersed on the exterior walls.

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Article information

DOI: https://doi.org/10.1039/C9CC00003H
Article type: Communication
Submitted: 01 Jan 2019
Accepted: 15 Mar 2019
First published: 27 Mar 2019

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Chem. Commun., 2019,55, 4699-4702

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Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

H. Zhang, M. Huang, J. Wen, Y. Li, A. Li, L. Zhang, A. M. Ali and Y. Li, Chem. Commun., 2019, 55, 4699 DOI: 10.1039/C9CC00003H

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Chemical Communications

Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation†

Abstract

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Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

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