Constructing and finely tuning the CO2 traps of stable and various-pore-containing MOFs towards highly selective CO2 capture

Xiaohui Song; Mingxing Zhang; Jingui Duan; Junfeng Bai

doi:10.1039/C8CC10116G

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Constructing and finely tuning the CO₂ traps of stable and various-pore-containing MOFs towards highly selective CO₂ capture†

Xiaohui Song,

‡^a Mingxing Zhang,

‡^b Jingui Duan

^c and Junfeng Bai

*^ad

Author affiliations

* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
E-mail: bjunfeng@nju.edu.cn

^b Department of Chemistry, Chongqing Normal University, Chongqing 401331, China

^c State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China

^d School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710119, China
E-mail: bjunfeng@snnu.edu.cn

Abstract

For real-life CO₂ capture, through the construction and fine tuning of the traps in metal–organic frameworks, we synthesized NJU-Bai51 with the combined features of high capacity, high selectivity and high water-stability, confirmed via breakthrough experiments, and its specific binding interaction was revealed from crystallographic measurements.

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Article information

DOI: https://doi.org/10.1039/C8CC10116G
Article type: Communication
Submitted: 21 Dec 2018
Accepted: 22 Feb 2019
First published: 22 Feb 2019

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Chem. Commun., 2019,55, 3477-3480

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Constructing and finely tuning the CO₂ traps of stable and various-pore-containing MOFs towards highly selective CO₂ capture

X. Song, M. Zhang, J. Duan and J. Bai, Chem. Commun., 2019, 55, 3477 DOI: 10.1039/C8CC10116G

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Chemical Communications