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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

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Abstract

A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C2-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.

Graphical abstract: A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

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Publication details

The article was received on 04 Dec 2018, accepted on 08 Jan 2019 and first published on 09 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC09643K
Citation: Chem. Commun., 2019, Advance Article
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    A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

    A. Nagai, T. Nakamura and T. Nabeshima, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09643K

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