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Formation of an interlocked double-chain from an organic–inorganic [2]rotaxane

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Abstract

Here we show that a structure containing a polymeric interlocking daisy chain is obtained from the reaction of an inorganic–organic [2]rotaxane [HB{CrIII7NiII(μ-F)8(O2CtBu)16}], where B is an organic thread terminated with a bi-pyridyl unit, with an oxo-centered metal carboxylate triangle [FeIII2CoII3-O)(O2CtBu)6(HO2CtBu)3].

Graphical abstract: Formation of an interlocked double-chain from an organic–inorganic [2]rotaxane

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Publication details

The article was received on 23 Nov 2018, accepted on 11 Feb 2019 and first published on 11 Feb 2019


Article type: Communication
DOI: 10.1039/C8CC09339C
Citation: Chem. Commun., 2019, Advance Article

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    Formation of an interlocked double-chain from an organic–inorganic [2]rotaxane

    J. Ferrando-Soria, A. Fernandez, I. J. Vitorica-Yrezabal, D. Asthana, C. A. Muryn, F. Tuna, G. A. Timco and R. E. P. Winpenny, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC09339C

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