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Issue 6, 2019
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Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration

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Abstract

A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(I) migration.

Graphical abstract: Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(i) migration

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Publication details

The article was received on 20 Nov 2018, accepted on 14 Dec 2018 and first published on 14 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09238A
Citation: Chem. Commun., 2019,55, 838-841
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    Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration

    R. E. Ruscoe, M. Callingham, J. A. Baker, S. E. Korkis and H. W. Lam, Chem. Commun., 2019, 55, 838
    DOI: 10.1039/C8CC09238A

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