Issue 8, 2019

Grubbs catalysts in intramolecular carbene C(sp3)–H insertion reactions from α-diazoesters

Abstract

Grubbs catalysts are described as a useful alternative to promote intramolecular carbene C–H insertion from α-diazoesters. Moreover, no competition arises from the possible metathesis reactions on substrates bearing alkene and alkyne moieties. DFT calculations were also carried out to gain insight into the reaction mechanism involved in these transformations.

Graphical abstract: Grubbs catalysts in intramolecular carbene C(sp3)–H insertion reactions from α-diazoesters

Supplementary files

Article information

Article type
Communication
Submitted
15 Nov 2018
Accepted
02 Jan 2019
First published
03 Jan 2019

Chem. Commun., 2019,55, 1160-1163

Grubbs catalysts in intramolecular carbene C(sp3)–H insertion reactions from α-diazoesters

D. Solé, A. Amenta, M. Bennasar and I. Fernández, Chem. Commun., 2019, 55, 1160 DOI: 10.1039/C8CC09089K

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