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Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

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Abstract

Partial dehydrobromination of a diprotic pincer-type ruthenium complex in the presence of a rigid 1,3-bis(diphenylphosphino)benzene linker provided a dinuclear cage containing a guest template KBr surrounded by hydrogen bonds and electrostatic interactions. Dinitrogen and carbon disulfide were encapsulated into the cage with proton channels formed by the pyrazole arms in the pincer ligands.

Graphical abstract: Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

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Publication details

The article was received on 19 Oct 2018, accepted on 30 Nov 2018 and first published on 30 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08384C
Citation: Chem. Commun., 2019, Advance Article
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    Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

    T. Toda, S. Suzuki and S. Kuwata, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC08384C

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