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A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

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Abstract

A homochiral open-framework fluorinated cobalt phosphate with a 2-fold interpenetrating diamond topology was ionothermally synthesized. The significant enantiomeric excess of the bulk product was confirmed by strong signals in its solid state circular dichroism (CD) spectrum.

Graphical abstract: A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

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Publication details

The article was received on 04 Sep 2018, accepted on 28 Nov 2018 and first published on 29 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC07161F
Citation: Chem. Commun., 2019, Advance Article
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    A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

    X. Tong, C. Jing, Z. Dong, N. Zhang, L. Bi, Y. Wang, H. Cai, D. An, X. Lian, Q. Wang, Q. Zhou, Y. Guo, Y. Yan and W. Yan, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C8CC07161F

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