A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

Xiaoqiang Tong; Chaojie Jing; Zhaojun Dong; Na Zhang; Lijun Bi; Yanyan Wang; Hua Cai; Dongmin An; Xiaoxue Lian; Qiong Wang; Qingjun Zhou; Ying Guo; Yan Yan; Wenfu Yan

doi:10.1039/C8CC07161F

A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality†

Xiaoqiang Tong,

*^a Chaojie Jing,^a Zhaojun Dong,^b Na Zhang,^c Lijun Bi,^a Yanyan Wang,^d Hua Cai,^a Dongmin An,^a Xiaoxue Lian,^a Qiong Wang,^a Qingjun Zhou,^a Ying Guo,^a Yan Yan^e and Wenfu Yan

^e

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* Corresponding authors

^a College of Science, Civil Aviation University of China, Tianjin 300300, P. R. China
E-mail: xqtong@cauc.edu.cn

^b College of Environment and Resources, Jilin University, Changchun 130012, P. R. China

^c Hainan Airlines Holding Company Limited, Haikou 570203, P. R. China

^d College of Chemistry and Chemical Engineering, Shaanxi Normal Normal University, Xi'an 710119, P. R. China

^e State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Abstract

A homochiral open-framework fluorinated cobalt phosphate with a 2-fold interpenetrating diamond topology was ionothermally synthesized. The significant enantiomeric excess of the bulk product was confirmed by strong signals in its solid state circular dichroism (CD) spectrum.

Chemical Communications

A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality†

Abstract

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A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

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