Carbonization of covalent triazine-based frameworks via ionic liquid induction

Jiangtao Jia; Zhijie Chen; Youssef Belmabkhout; Karim Adil; Prashant M. Bhatt; Vera A. Solovyeva; Osama Shekhah; Mohamed Eddaoudi

doi:10.1039/C8TA05583A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Carbonization of covalent triazine-based frameworks via ionic liquid induction†

Jiangtao Jia,

^a Zhijie Chen,

^a Youssef Belmabkhout,

^a Karim Adil,

^a Prashant M. Bhatt,

^a Vera A. Solovyeva,

^a Osama Shekhah

^a and Mohamed Eddaoudi

*^a

Author affiliations

* Corresponding authors

^a Functional Materials Design, Discovery & Development Research Group (FMD3), Advanced Membranes & Porous Materials Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
E-mail: mohamed.eddaoudi@kaust.edu.sa

Abstract

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl₂ as an ionic liquid were allowed to alter/enhance the Brunauer–Emmett–Teller (BET) surface areas of the POPs in the range from 760 to 1560 m² g⁻¹. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

Download options Please wait...

Supplementary files

Supplementary information PDF (928K)

Article information

DOI: https://doi.org/10.1039/C8TA05583A
Article type: Communication
Submitted: 12 Jun 2018
Accepted: 25 Jul 2018
First published: 25 Jul 2018

Download Citation

J. Mater. Chem. A, 2018,6, 15564-15568

Permissions

Request permissions

Carbonization of covalent triazine-based frameworks via ionic liquid induction

J. Jia, Z. Chen, Y. Belmabkhout, K. Adil, P. M. Bhatt, V. A. Solovyeva, O. Shekhah and M. Eddaoudi, J. Mater. Chem. A, 2018, 6, 15564 DOI: 10.1039/C8TA05583A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Journal of Materials Chemistry A

Carbonization of covalent triazine-based frameworks via ionic liquid induction†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Carbonization of covalent triazine-based frameworks via ionic liquid induction

Social activity

Search articles by author

Spotlight

Advertisements