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Issue 36, 2018
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Water adsorption at zirconia: from the ZrO2(111)/Pt3Zr(0001) model system to powder samples

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Abstract

We present a comprehensive study of water adsorption and desorption on an ultrathin trilayer zirconia film using temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), as well as scanning tunneling microscopy (STM) at different temperatures. The saturation coverage is one H2O per surface Zr atom, with about 12% dissociation. The monolayer TPD peak (180 K, desorption barrier 0.57 ± 0.04 eV) has a tail towards higher temperatures, caused by recombinative desorption from defect sites with dissociated water. STM shows that the defects with the strongest H2O adsorption are found above subsurface dislocations. Additional defect sites are created by multiple water adsorption/desorption cycles; these water-induced changes were also probed by CO2 TPD. Nevertheless, the defect density is much smaller than in previous studies of H2O/ZrO2. To validate our model system, transmission Fourier-transform infrared absorption spectroscopy (FTIR) studies at near-ambient pressures were carried out on monoclinic zirconia powder, showing comparable adsorption energies as TPD on the ultrathin film. The results are also compared with density functional theory (DFT) calculations, which suggest that sites with strong H2O adsorption contain twofold-coordinated oxygen.

Graphical abstract: Water adsorption at zirconia: from the ZrO2(111)/Pt3Zr(0001) model system to powder samples

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Publication details

The article was received on 04 May 2018, accepted on 05 Aug 2018 and first published on 31 Aug 2018


Article type: Paper
DOI: 10.1039/C8TA04137G
Citation: J. Mater. Chem. A, 2018,6, 17587-17601
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    Water adsorption at zirconia: from the ZrO2(111)/Pt3Zr(0001) model system to powder samples

    P. Lackner, J. Hulva, E. Köck, W. Mayr-Schmölzer, J. I. J. Choi, S. Penner, U. Diebold, F. Mittendorfer, J. Redinger, B. Klötzer, G. S. Parkinson and M. Schmid, J. Mater. Chem. A, 2018, 6, 17587
    DOI: 10.1039/C8TA04137G

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