Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

Monika Gosecka; Malgorzata Urbaniak; Maciej Mikina; Mateusz Gosecki; Artur Rozanski

doi:10.1039/C8SM01777H

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Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)†

Monika Gosecka,

*^a Malgorzata Urbaniak,^a Maciej Mikina,^b Mateusz Gosecki^a and Artur Rozanski^a

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* Corresponding authors

^a Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Polymer Division, ul. Sienkiewicza 112, 90-36 Lodz, Poland
E-mail: mdybko@cbmm.lodz.pl

^b Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Division of Organic Chemistry, ul. Sienkiewicza 112, 90-36 Lodz, Poland

Abstract

We present an unexpected self-assembly of a glycoluril clip–poly(ε-caprolactone) conjugate in chloroform. The conjugate forms homodimer aggregates due to supramolecular interactions between glycoluril moieties, which was confirmed with MALDI-TOF-ms and ¹H NMR. TEM revealed the formation of multilayered nanosized prism-shaped objects resembling tree bark in nature.

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Article information

DOI: https://doi.org/10.1039/C8SM01777H
Article type: Communication
Submitted: 30 Aug 2018
Accepted: 11 Sep 2018
First published: 13 Sep 2018

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Soft Matter, 2018,14, 7945-7949

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Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

M. Gosecka, M. Urbaniak, M. Mikina, M. Gosecki and A. Rozanski, Soft Matter, 2018, 14, 7945 DOI: 10.1039/C8SM01777H

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Soft Matter

Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)†

Abstract

Supplementary files

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Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

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