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Issue 39, 2018
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Multi-stimuli-responsiveness of a novel polydiacetylene-based supramolecular gel

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Abstract

Herein, a novel supramolecular gel was fabricated through the bi-component co-assembly strategy of commercially available 10,12-pentacosadiynoic acid (PCDA) and laboratory-synthesized amphiphilic co-gelator N-(2-(1H-imidazol-4-yl)ethyl)stearamide (IMSA), which contains one imidazole head group and a long alkyl chain tail, by synergetic noncovalent interactions. Upon irradiation of normal 254 nm UV light, blue polydiacetylene (PDA) could be obtained by topo-polymerization of the PCDA monomers in the gel phase. This PDA-based supramolecular gel is able to respond to various environmental stimuli and shows a blue-to-red chromatic transition, which could be observed by the naked eye. Specifically, upon exposure to heat, pH, metal cation and organic solvent stimuli, the PDA gel displays thermochromism, halochromism, ionochromism and solvatochromism, respectively. More interestingly, the differences of the above-mentioned stimuli-induced color transition of the blue PDA supramolecular gels could be characterized by UV-Vis absorption spectra and Raman spectra, therefore illuminating a bright application prospect in the area of chemosensing.

Graphical abstract: Multi-stimuli-responsiveness of a novel polydiacetylene-based supramolecular gel

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Publication details

The article was received on 25 Jul 2018, accepted on 09 Sep 2018 and first published on 10 Sep 2018


Article type: Paper
DOI: 10.1039/C8SM01515E
Citation: Soft Matter, 2018,14, 8044-8050
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    Multi-stimuli-responsiveness of a novel polydiacetylene-based supramolecular gel

    Y. Xu, S. Fu, F. Liu, H. Yu and J. Gao, Soft Matter, 2018, 14, 8044
    DOI: 10.1039/C8SM01515E

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