Issue 22, 2018

Rheological behavior and mechanism of pH-responsive wormlike micelle variations induced by isomers of phthalic acid

Abstract

Responsive wormlike micelles (WLMs) constructed by different carboxylic acids are fascinating. However, it is unknown how the position of the carboxylic groups alters the stimuli-response of wormlike micellar systems. Herein, three pH-responsive WLMs based on Gemini-like surfactants (named o-EAPA, m-EAPA, and p-EAPA) were formed and studied through the complexation of N-erucamidopropyl-N,N-dimethylamine (UC22AMPM) and o-phthalic acid (o-PA), m-phthalic acid (m-PA), or p-phthalic acid (p-PA) at the molar ratio of 2 : 1. The viscoelasticity, phase behavior and aggregate microstructure were separately explored by rheological, appearance observation and cryo-TEM methods. The results show that all phthalic acids can protonate UC22AMPM, thereby forming WLMs. However, with the shorter spacer distance between two carboxyl groups in phthalic acid, o-EAPA exhibits the longer length scale of aggregates and a more efficient thickening ability compared to the other two systems. Similar results in the N,N-dimethyl oleoaminde-propylamine (DOAPA) and o-PA, m-PA, and p-PA systems further verify the applicability of this mechanism. Furthermore, the phthalic acid based WLMs are found to exhibit intriguing reversible pH-responsive behaviors, which include promptly switching between a high elastic system and a low viscosity fluid by pH control. The o-EAPA system possesses a larger viscosity maximum, which produces more precipitous viscosity changes as the pH varies. This study is beneficial for the formation of pH-responsive WLMs and to determine their advantages for applications.

Graphical abstract: Rheological behavior and mechanism of pH-responsive wormlike micelle variations induced by isomers of phthalic acid

Article information

Article type
Paper
Submitted
06 Mar 2018
Accepted
16 Apr 2018
First published
16 Apr 2018

Soft Matter, 2018,14, 4445-4452

Rheological behavior and mechanism of pH-responsive wormlike micelle variations induced by isomers of phthalic acid

W. Kang, Y. Zhao, P. Wang, Z. Li, X. Hou, Z. Huang and H. Yang, Soft Matter, 2018, 14, 4445 DOI: 10.1039/C8SM00467F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements