Study of the structure and characteristics of mesoporous TiO2 photocatalyst, and evaluation of its factors on gaseous formaldehyde removal by the analysis of ANOVA and S/N ratio

Abstract

This study differs from previous studies of TiO₂/SiO₂ in that 0.5–10 μm microsized TiO₂-rutile based catalysts (TR catalysts) with varying proportions of titanium and silicon were synthesized using a one-step modified hydrothermal method. At Ti/Si = 1/9, a two-dimensional channel-structured catalyst with a morphology resembling that of SBA-15 was obtained. In contrast, at Ti/Si = 3/7 or 5/5, a three-dimensional porous structure was formed, and Ti–O–Si–C bonds appeared. The structure of the TR catalyst transformed due to the decrease in C–Si bond content and the increase in C–C bond content with increasing Ti/Si ratio. The results indicated that the rutile phase was the main crystal phase of the TR catalyst. The small crystal size and large rutile phase content of the mesoporous TR catalyst contributed to the low band gap energy below 3.0 eV. Under 2 × 10 W lamp irradiation with either UVA or visible light, the three TR catalysts showed better formaldehyde (HCHO) removal efficiency than P25. Furthermore, the Taguchi method was employed to evaluate the catalytic factors by analysis of variance (ANOVA) and S/N ratio. The results revealed the contributions of each of the three factors to HCHO removal efficiency over TR catalysts to be as follows: space velocity (62%), Ti ratio (32%), and time on stream (5%). The TR catalyst with Ti/Si = 1/9 showed good HCHO removal efficiency with a high S_BET (787.1 m² g⁻¹) and large pore volume (0.95 cm³ g⁻¹) for a residence time of over 2.29 × 10⁻¹ s under visible light irradiation. Microwave-assisted EG reduction was successfully applied to dope a TR catalyst with nanosized Pt particles in a short synthesis time. After Pt doping, the removal efficiency in the stream improved and stabilized. The Pt particles were Pt⁰ and proved effective for improving the photocatalytic removal of HCHO over the TR catalyst by prolonging the separation time of the electron–hole pairs. Overall, the Pt/TR catalyst is a potential material for pollutant removal and can be easily separated from the pollutant removal system since the catalysts are microsized.