Issue 30, 2018, Issue in Progress

Effect of fluorination of naphthalene diimide–benzothiadiazole copolymers on ambipolar behavior in field-effect transistors

Abstract

Two naphthalene diimide (NDI)–benzothiadiazole (BT) based conjugated polymers with high molecular weight, P1 and P2, were synthesized by introducing F atoms to modulate the electron-donating ability of the BT moiety. 3-Decyl-pentadecyl branched alkyl side chains were employed and expected to improve the molecular organization and device performance. Both polymers have excellent solubility in common organic solvents. UV-vis-NIR absorption and cyclic voltammetry indicate that the maximum absorption wavelength of P2 is blue-shifted and the HOMO energy level of P2 is decreased in comparison with P1. Two dimensional wide angle X-ray scattering of thin films revealed a similar organization of both polymers. A less balanced transport in field-effect transistors with increased electron mobility of 0.258 cm2 V−1 s−1 and lowered hole transport of 2.4 × 10−3 cm2 V−1 s−1 was found for P2. Polymer devices of P1 exhibited a balanced ambipolar transport, with a hole mobility of 0.073 cm2 V−1 s−1 and electron mobility of 0.086 cm2 V−1 s−1.

Graphical abstract: Effect of fluorination of naphthalene diimide–benzothiadiazole copolymers on ambipolar behavior in field-effect transistors

Supplementary files

Article information

Article type
Paper
Submitted
04 Apr 2018
Accepted
29 Apr 2018
First published
03 May 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 16464-16469

Effect of fluorination of naphthalene diimide–benzothiadiazole copolymers on ambipolar behavior in field-effect transistors

C. An, H. Makowska, B. Hu, R. Duan, W. Pisula, T. Marszalek and M. Baumgarten, RSC Adv., 2018, 8, 16464 DOI: 10.1039/C8RA02915F

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