84% efficiency improvement in all-inorganic perovskite light-emitting diodes assisted by a phosphorescent material

Abstract

A novel mixed perovskite emitter layer is applied to design all-inorganic cesium lead halide perovskite light-emitting diodes (PeLEDs) with high electroluminescence (EL) performance, by combining CsPbBr₃ with iridium(III)bis[2-(4′,6′-difluorophenyl)pyridinato-N,C²′]-picolinate (FIrpic), where FIrpic is a phosphorescent material with very high internal quantum efficiency (IQE) approaching 100%. The CsPbBr₃:FIrpic PeLEDs show a maximum luminance of 5486 cd m⁻², and an external quantum efficiency of 0.47%, which are 1.84 and 1.76 times that of neat CsPbBr₃ PeLEDs, respectively. It is found that FIrpic molecules as an assistant dopant can efficiently transmit energy from the excitons of FIrpic to the excited state of the CsPbBr₃ emitter via a Förster energy transfer process, leading to enhanced EL efficiency in the CsPbBr₃:FIrpic PeLEDs.