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Issue 15, 2018, Issue in Progress
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UV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions

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Abstract

A UV-mediated hydrophosphinylation of unactivated alkenes with H-phosphinates and hypophosphorous acid under radical free conditions is presented. The reaction affords selectively a large number of structurally diverse organophosphorous compounds in moderate to good yields under mild reaction conditions in the presence of an organic sensitizer as catalyst irradiated by UV-A LEDs. Furthermore, the high yielding hydrophosphinylation in continuous flow is disclosed.

Graphical abstract: UV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions

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Publication details

The article was received on 01 Dec 2017, accepted on 18 Feb 2018 and first published on 23 Feb 2018


Article type: Paper
DOI: 10.1039/C7RA12977G
RSC Adv., 2018,8, 8385-8392
  • Open access: Creative Commons BY license
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    UV-mediated hydrophosphinylation of unactivated alkenes with phosphinates under batch and flow conditions

    F. Gelat, M. Roger, C. Penverne, A. Mazzad, C. Rolando and L. Chausset-Boissarie, RSC Adv., 2018, 8, 8385
    DOI: 10.1039/C7RA12977G

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