Synthesis and properties of a POM-based trinuclear copper(ii) triazole framework

Abstract

A novel POM-based trinuclear copper(II) triazole framework, namely, [H₂{Cu₆(trz)₆(μ₃-OH)₂}Mo₅O₁₈]·3H₂O (1) was isolated using a hydrothermal method, which displays a 3D network constructed from trinuclear copper(II) units and triazole ligands with [Mo₅O₁₈]⁶⁻ anions as templates. 1 has been identified by single crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and FT-IR. Magnetic studies indicate that antiferromagnetic interactions exist in 1. In addition, 1 exhibits good Lewis acid catalytic activity for the synthesis of cyclohexanone ethylene ketal with 95% conversion. The HOMO–LUMO gap (E_g) of 1 is 2.34 eV calculated using the Kubelka–Munk equation (Fhν)^0.5, indicating that its forbidden bandwidth belongs to the semiconductor category. Visible-light photodegradation of RhB catalyzed by 1 was investigated, which shows high activity with an above 98% degradation rate.