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Issue 2, 2019
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Manganese(III)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

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Abstract

A simple and direct method for the preparation of β-phosphoryl enamides has been achieved through Mn(III)-mediated radical oxidative selective phosphorylation of N-styrylamides. The reaction could be efficiently scaled-up and the products could be easily transformed into β-amino phosphonic acid, a bio-isostere of the corresponding amino acid.

Graphical abstract: Manganese(iii)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

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Publication details

The article was received on 12 Oct 2018, accepted on 11 Dec 2018 and first published on 12 Dec 2018


Article type: Research Article
DOI: 10.1039/C8QO01098F
Citation: Org. Chem. Front., 2019,6, 236-240
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    Manganese(III)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

    D. Zhang, C. Li, R. Zeng, A. Shoberu and J. Zou, Org. Chem. Front., 2019, 6, 236
    DOI: 10.1039/C8QO01098F

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